[1'-(9-fluorenyl)-2'-(cyclopentadienyl)naphthalene]zirconium dichloride | 719278-32-7

• 英文名称: [1'-(9-fluorenyl)-2'-(cyclopentadienyl)naphthalene]zirconium dichloride
• CAS: 719278-32-7
• 化学式: C₂₈H₁₈Cl₂Zr
• 分子量: 516.581
• InChiKey: PTPPDPIXBJBNQB-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  氯化锆(IV) 、 9-[2'-(1",3"-cyclopenadien-1"-yl)-1'-naphthyl]-fluorene 、 9-[2'-(1",3"-cyclopenadien-2"-yl)-1'-naphthyl]-fluorene 在 n-butyllithium 作用下， 以 苯 为溶剂， 以51%的产率得到[1'-(9-fluorenyl)-2'-(cyclopentadienyl)naphthalene]zirconium dichloride
  参考文献：
  名称：

  Zirconocene dichloride complexes with a 1,2-naphthylidene bridge as catalysts for the polymerisation of ethylene and propylene

  摘要：

  Ansa-zirconocene dichloride complexes containing a 9-fluorenyl group at the 1-position of naphthalene and a 2-indenyl 12, 1-indenyl 13, or cyclopentadienyl 14 group at the 2-position of the naphthalene were synthesised and characterised. The molecular structures of the complexes have been determined by single crystal X-ray diffraction studies. After activation with excess methyl-alumoxane (MAO). the complexes were used as homogeneous catalysts for the homopolymerisation of ethylene and propylene. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.021