| 181471-68-1

• CAS: 181471-68-1
• 化学式: C₂₂H₂₆SiZr
• 分子量: 409.758
• InChiKey: BIUVTGDMBLRSNI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 四氢呋喃 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  Cross-conjugated polymers via condensation of a zirconocene alkynyl(benzyne) derivative generated by thermolysis of Cp2ZrMe(C6H4CCSiMe3)

  摘要：

  The complex Cp(2)ZrMe(C6H4C=CSiMe(3)) (4) has been synthesized by reaction of Cp(2)ZrMeCl and LiC6H4C=CSiMe(3) (generated in situ from reaction of (n)BuLi with BrC6H4C=CSiMe(3) at -95 degrees C). Thermolysis of 4 in THF afforded an unsaturated, organometallic polymer [Cp(2)Zr(C6H3C=CSiMe(3))](n) (7) in ca. 80% yield (M(w)/M(n) = 4000/2000). Polymer 7 was investigated as a synthon for other unsaturated polymers. It reacts with hydrochloric acid to form a new phenylene-1,1-vinylene polymer [-C(=CHSiMe(3))-1,4-C6H4-](n) (8), and with sulfur dichloride to give poly(1-trimethylsilyl-2-benzo[b]thiophene) (9). ?Thermolysis of two similar compounds, Cp(2)ZrMe(C6H4C=CCH3) (5) and Cp(2)ZrMe(C6H4C6H4C=CSiMe(3)) (6), did not give polymers.

  DOI：

  10.1016/0022-328x(96)06353-x
• 作为产物：
  描述：

  zirconocene methyl chloride 、 (4-溴苯基乙炔基)三甲基硅烷 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Cross-conjugated polymers via condensation of a zirconocene alkynyl(benzyne) derivative generated by thermolysis of Cp2ZrMe(C6H4CCSiMe3)

  摘要：

  The complex Cp(2)ZrMe(C6H4C=CSiMe(3)) (4) has been synthesized by reaction of Cp(2)ZrMeCl and LiC6H4C=CSiMe(3) (generated in situ from reaction of (n)BuLi with BrC6H4C=CSiMe(3) at -95 degrees C). Thermolysis of 4 in THF afforded an unsaturated, organometallic polymer [Cp(2)Zr(C6H3C=CSiMe(3))](n) (7) in ca. 80% yield (M(w)/M(n) = 4000/2000). Polymer 7 was investigated as a synthon for other unsaturated polymers. It reacts with hydrochloric acid to form a new phenylene-1,1-vinylene polymer [-C(=CHSiMe(3))-1,4-C6H4-](n) (8), and with sulfur dichloride to give poly(1-trimethylsilyl-2-benzo[b]thiophene) (9). ?Thermolysis of two similar compounds, Cp(2)ZrMe(C6H4C=CCH3) (5) and Cp(2)ZrMe(C6H4C6H4C=CSiMe(3)) (6), did not give polymers.

  DOI：

  10.1016/0022-328x(96)06353-x