| 53787-11-4

• CAS: 53787-11-4
• 化学式: C₁₆H₄₈F₈N₈Ti₄
• 分子量: 696.118
• InChiKey: VLGLWPIFLPKKRY-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrakis(dimethylamido)titanium(IV) 、 四氟化钛 以 乙腈 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of [TiF2(NMe2)2]4 and its use for olefin polymerizations

  摘要：

  An equimolar mixture of TiF4 and Ti(NMe2)(4) in CH3CN gave orange crystals of [TiF2(NMe2)(2)](4) in good yield. This complex is a cyclic tetramer of TiF2(NMe2)(2), where each titanium atom is bonded to one terminal fluoride and terminal amide ligands and to two pairs of bridging fluoride and bridging amide ligands. This complex was employed as a catalyst for polymerizations of ethylene, propylene, and styrene in the presence of methylaluminoxane (MAO); the activity was relatively low for these olefin polymerizations. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01515-3