(6-(CH2NMe2)2-CPh3-4-Me-C6H4O)AlMeCl | 916249-51-9

• 英文名称: (6-(CH2NMe2)2-CPh3-4-Me-C6H4O)AlMeCl
• CAS: 916249-51-9
• 化学式: C₃₀H₃₁AlClNO
• 分子量: 484.017
• InChiKey: BIBNQJWJXNDOGE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 (6-(CH2NMe2)2-CPh3-4-Me-C6H4O)AlMeCl 、 三(五氟苯基)硼烷 以 二氯甲烷-D2 为溶剂， 生成 (6-(CH2NMe2)2-CPh3-4-Me-C6H4O)AlCl2 、 [(6-(CH2NMe2)2-CPh3-4-Me-C6H4O)Al(Me)(THF)][MeB(C6F5)3]
  参考文献：
  名称：

  Reactivity studies of a four-coordinate methyl chloro aluminium aminophenolate complex with B(C6F5)3

  摘要：

  The X-ray characterized four-coordinate aminophenolate aluminium complex {6-(CH2NMe2)-2-CPh3-4-Me-C6H2O}Al(Me)(Cl) (1), which is readily available by reaction of the corresponding aminophenolate Li salt with MeAlCl2, slowly reacts with B(C6F5)(3) to yield a 1/1 mixture of the Al methyl cation {6-(CH2NMe2)-2-CPh3-4-Me-C6H2O}Al(Me)(THF)(+) (2, as MeB(C6F5)(3)(-) salt) and the Al dichloro derivative {6-(CH2NMe2)-2-CPh3-4-Me-C6H2O}AlCl2 (3). This reaction most likely proceeds via a Me- abstraction/ligand exchange sequence. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.07.001
• 作为产物：
  描述：

  [6-(CH2NMe2)2-CPh3-4-Me-C6H4O]Li 、 甲基二氯化铝 以 正己烷 、 甲苯 为溶剂， 以55%的产率得到(6-(CH2NMe2)2-CPh3-4-Me-C6H4O)AlMeCl
  参考文献：
  名称：

  Reactivity studies of a four-coordinate methyl chloro aluminium aminophenolate complex with B(C6F5)3

  摘要：

  The X-ray characterized four-coordinate aminophenolate aluminium complex {6-(CH2NMe2)-2-CPh3-4-Me-C6H2O}Al(Me)(Cl) (1), which is readily available by reaction of the corresponding aminophenolate Li salt with MeAlCl2, slowly reacts with B(C6F5)(3) to yield a 1/1 mixture of the Al methyl cation {6-(CH2NMe2)-2-CPh3-4-Me-C6H2O}Al(Me)(THF)(+) (2, as MeB(C6F5)(3)(-) salt) and the Al dichloro derivative {6-(CH2NMe2)-2-CPh3-4-Me-C6H2O}AlCl2 (3). This reaction most likely proceeds via a Me- abstraction/ligand exchange sequence. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.07.001