PhSnCl2(4-methyl-1-piperidine dithiocarboxylate) | 286401-55-6

• 英文名称: PhSnCl2(4-methyl-1-piperidine dithiocarboxylate)
• CAS: 286401-55-6
• 化学式: C₁₃H₁₇Cl₂NS₂Sn
• 分子量: 441.033
• InChiKey: RVVPCRHNCALEQV-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-methyl-1-piperidine dithiocarbamic acid 、 苯基三氯化锡 以 氯仿 为溶剂， 以72%的产率得到PhSnCl2(4-methyl-1-piperidine dithiocarboxylate)
  参考文献：
  名称：

  Synthesis and spectral characterization of chloro-organotin(IV) complexes of S-donor ligand: Crystal structure of chloro-t-dibutyltin[4-methyl-1-piperidine]thiocarboxylate

  摘要：

  New chloromono- and diorganotin(IV) complexes of 4-methyl-1-piperidine dithiocarboxylic acid have been synthesized in anhydrous chloroform. The complexes were characterized by microanalysis, IR, H-1 and C-13 NMR, mass spectrometry and XRD. The FTIR spectra clearly demonstrate that organotin(IV) moieties react with [S,S] atoms of the ligand. Compound (1) and (3) exhibits the 5-coordinated while the compound (2) exhibit 6-coordinated geometry in solid state. Compound (3) shows distorted trigonal bipyramidal geometry which is confirmed by X-ray single-crystal diffraction.

  DOI：

  10.1134/s0036023612050117