[(n-Bu)2Sn2O[O2P(OH)-t-Bu]4]2 | 124358-16-3

• 英文名称: [(n-Bu)2Sn2O[O2P(OH)-t-Bu]4]2
• CAS: 124358-16-3
• 化学式: C₄₈H₁₁₆O₂₆P₈Sn₄
• 分子量: 1832.06
• InChiKey: YPEWLGDNVYRVDB-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  叔丁基磷酸 、 丁基锡酸 以 neat (no solvent, solid phase) 为溶剂， 以92%的产率得到[(n-Bu)2Sn2O[O2P(OH)-t-Bu]4]2
  参考文献：
  名称：

  Solventless Reactions for the Synthesis of Organotin Clusters and Cages

  摘要：

  Organotin clusters and cages have been synthesized in quantitative yields by using a benign solventless synthetic methodology. Using this method a variety of structural forms, which include the drum, O-capped cluster, tetranuclear oxo cage, discrete, and polymeric compounds, have been synthesized. All these compounds (1-11) have been characterized by spectroscopic and analytical techniques. The new compounds, which include the hexameric drum [n-BuSn-(O)OCOAd](6) (Ad = adamantyl) 9, a triorganotin-based discrete structure Ph3SnO2C-C(6)H(2-)2,4,6-Me-3 (10), and a polymer Ph3SnOSO2-C6H3-2,5-Me-2 (11), have been characterized by single-crystal X-ray crystallography.

  DOI：

  10.1021/om030338c