(2-(7-(4-bromophenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline)chloridoplatimun(II) | 1373627-34-9

• 英文名称: (2-(7-(4-bromophenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline)chloridoplatimun(II)
• CAS: 1373627-34-9
• 化学式: C₆₅H₈₂BrClN₂Pt
• 分子量: 1201.82
• InChiKey: JUVOHSDZQPZELB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 2-(7-(4-bromophenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline 以 氯仿 、 溶剂黄146 为溶剂， 以33%的产率得到(2-(7-(4-bromophenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline)chloridoplatimun(II)
  参考文献：
  名称：

  Synthesis and photophysics of platinum(II) complexes bearing 2-(7-(4-R-phenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline ligand

  摘要：

  A series of platinum(II) complexes bearing 2-(7-(4-R-phenylethynyl)-9,9-dihexadecyl-fluoren-2-yl)-1,10-phenanthroline ligand were synthesized and characterized. Their photophysical properties were systematically investigated by UV-Vis absorption, emission, and transient absorption spectroscopy. All complexes exhibit (1)pi,pi* absorption bands below 410 nm and charge transfer transitions at 415-550 nm in CH2Cl2. They all emit at ca. 624 nm with vibronic structures. Both UV-Vis absorption and emission spectra show negative solvatochromic effect. All complexes exhibit broad and moderately strong triplet transient absorption from the near-UV to the near-IR spectral region. Reverse saturable absorption of these complexes in CH2Cl2 for ns laser pulses at 532 nm was demonstrated. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.03.033