In2Cl4(tetrahydrofuran)4 | 164985-37-9

• 英文名称: In2Cl4(tetrahydrofuran)4
• CAS: 164985-37-9
• 化学式: C₁₆H₃₂Cl₄In₂O₄
• 分子量: 659.88
• InChiKey: NXRDWHCKASOGST-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 三苯基膦氯金 、 indium chloride 以 四氢呋喃 为溶剂， 以40%的产率得到In2Cl4(tetrahydrofuran)4
  参考文献：
  名称：

  Different Pathways of the Reaction of InCl with Ph3PAuCl: Isolation of the First Mixed-Valent Mixed-Metal Gold/Indium Cluster

  摘要：

  In the absence of an auxiliary ligand, the title reaction led to redox products among which In2Cl4(thf)(2) has been identified as an In-In-bonded dinuclear In(II) complex. However, in the presence of Ph(2)PCH(2)CH(2)PPh(2) (dppe), a novel hexanuclear cluster of the formula Au3In3Cl6(dppe)(2) was produced, which is composed of a triangle of gold atoms (with one very short edge) penetrated by a perpendicular triangle of indium atoms.

  DOI：

  10.1021/ic00119a003