Ti(NNMe2)(2-((dimethylamino)methyl)pyrrolyl)[N(Bu(t))CHCHC(Bu(n))N(NMe2)-κ2N] | 897387-61-0

• 英文名称: Ti(NNMe2)(2-((dimethylamino)methyl)pyrrolyl)[N(Bu(t))CHCHC(Bu(n))N(NMe2)-κ2N]
• CAS: 897387-61-0
• 化学式: C₂₂H₄₃N₇Ti
• 分子量: 453.51
• InChiKey: VWWWHBJVVOKHCO-UORWCOPCSA-N

反应信息

• 作为产物：
  描述：

  1-己炔 、 异氰酸叔丁酯 、 偏二甲肼 、 [Ti(2-(N,N-dimethylaminomethyl)pyrrolyl)2(dimethylamido)2] 以 甲苯 为溶剂， 以94%的产率得到Ti(NNMe2)(2-((dimethylamino)methyl)pyrrolyl)[N(Bu(t))CHCHC(Bu(n))N(NMe2)-κ2N]
  参考文献：
  名称：

  Synthesis and Structure of a Titanium Hydrazido(2−) Complex

  摘要：

  Reaction of 1 equiv each of Ti(NMe2)(2)( dap)(2) ( 1), 1-hexyne, tert-butyl isocyanide, and 1,1-dimethylhydrazine at room temperature results in the formation of Ti(NNMe2)( dap)[ N(Bu-t) CHCHC(Bu-n) N(NMe2)-kappa N-2] ( 2), where one of the ligands is formed through iminohydrazination of the alkyne. A possible pathway for the generation of 2 and the crystal structure of this rare terminal hydrazido( 2-) complex of titanium are discussed.

  DOI：

  10.1021/om060304f