[η(2)-dihydrogen iron tetracarbonyl] | 234431-40-4

• 英文名称: [η(2)-dihydrogen iron tetracarbonyl]
• CAS: 234431-40-4
• 化学式: C₄H₂FeO₄
• 分子量: 169.904
• InChiKey: RQJZATPEFBOXNI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Fe(CO)4(η2-dinitrogen)] 、 氢气 以 solid matrix 为溶剂， 生成 [η(2)-dihydrogen iron tetracarbonyl]
  参考文献：
  名称：

  聚乙烯薄膜中的高压反应，是基质分离的新进展。Fe（CO）5与N 2的光化学反应和Fe（CO）4（N 2）与H 2的热反应

  摘要：

  A new miniature high-pressure cell has been developed for the spectroscopic study of reactions between organometallic compounds impregnated into polymer films and gases such as N2 or H-2 at any temperature between ambient and 20 K. The use of the cell is illustrated by the photochemical reactions of Fe(CO), in polyethylene film (PE) with N2 and H-2 at 190 K to form Fe(CO)4(N2) and Fe(CO)4H2 respectively. IR spectra suggest that the N2 group may occupy an equatorial rather than an axial position. Once formed. Fe(CO)4(N2) is shown to react thermally with H-2 at almost-equal-to 210 K to yield the dihydride compound, Fe(CO)4H2.

  DOI：

  10.1016/0009-2614(93)85493-8