NiCl2(bis[trimethylsilyliminodi(phenyl)phosphoranyl]methane)*0.5CH2Cl2 | 556112-67-5

• 英文名称: NiCl2(bis[trimethylsilyliminodi(phenyl)phosphoranyl]methane)*0.5CH2Cl2
• 英文别名: NiCl2[CH2(PPh2=NSiMe3)2]*0.5CH2Cl2；NiCl2(bis[trimethylsilyliminodi(phenyl)phosphoranyl]methane)*CH2Cl2；NiCl2[CH2(PPh2=NSiMe3)2]*CH2Cl2
• CAS: 556112-67-5
• 化学式: 0CH₂Cl₂*C₃₁H₄₀Cl₂N₂NiP₂Si₂
• 分子量: 730.853
• InChiKey: AROWGEWQENPXDB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯甲烷 、 bis[trimethylsilyliminodi(phenyl)phosphoranyl]methane 、 nickel dichloride 以 甲苯 为溶剂， 以11%的产率得到NiCl2(bis[trimethylsilyliminodi(phenyl)phosphoranyl]methane)*0.5CH2Cl2
  参考文献：
  名称：

  Reactions of the bis(iminophosphoranyl)methane ligand CH2(Ph2PNSiMe3)2 with nickel(II) halides and the structural characterization of ligand fragmentation products

  摘要：

  While anhydrous nickel(II) chloride reacts with CH2(Ph2P=NSiMe3)(2) to afford the pseudotetrahedral complex NiCl2[CH2(Ph2P=NSiMe3)(2)] (2), the analogous reaction with anhydrous nickel(II) iodide gives the structurally related complex NiI2[CH2(PPh2= NSiMe3)(PPh2=NH)] (3) in which one of the trimethylsilyl groups of 1 has been replaced by hydrogen. Another reaction in which the fragmentation of 1 occurs is that with the hydrate NiCl2-6H(2)O; in this case a square-planar nickel(II) complex of composition [Ni{Ph2PCH2PPh2(=NH)}(2)]Cl-1.25(NO3)(0.75) (4) was identified as one of the products. The phosphonium salt [Ph2P(NH2)-NPPh2(CH3)]I (5) is found to be a major product of the reaction between 3 and CO. The structures of 2-5 have been established by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01385-3