| 235756-15-7

• CAS: 235756-15-7
• 化学式: C₃₀H₆₄B₂MoN₄O₄P₂Si
• 分子量: 752.458
• InChiKey: NSXUJDGRJZYTAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) 、 bis([bis(diisopropylamino)boryl]phosphino)dimethylsilane 以 正己烷 为溶剂， 以57%的产率得到
  参考文献：
  名称：

  Coordination chemistry of aminoborylphosphanes. Crystal structure determinations of (iPr2N)2BP(H)SiPh3·Cr(CO)5 and [(iPr2N)2BP(H)]2SiMe2·W(CO)4

  摘要：

  The reactions of the aminoborylphosphanes, ((Pr2N)-Pr-i)(2)BP(H)SiPh3 (1), [((Pr2N)-Pr-i)(2)BP(H)](2)siMe(2) (2), and [((Pr2N)-Pr-i)(2)SP(H) Si(Me)(2)](2) (3) with M(CO)(5). NMe3 or M(CO)(4) (norbornadiene) (M = Cr, Mo, W) gave solid, crystalline adducts, three of which have been fully characterized. The molecular structures of ((Pr2N)-Pr-i)(2)BP(H)SiPh3. Cr(CO)(5) (4) and [((Pr2N)-Pr-i)(2)BP(H)](2)SiMe2 .W(CO)(4) (5') have been determined by single crystal X-ray diffraction techniques. Ligand 1 acts as a monodentate sigma donor ligand while 2 coordinates as a chelating phosphane. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01181-4