| 850012-89-4

• CAS: 850012-89-4
• 化学式: C₁₉H₁₉ClCuN₃O₄*Cl
• 分子量: 487.83
• InChiKey: GSAGEPIWGOYVNX-NWMPYMMKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 copper(II) choride dihydrate 、 [6-(吡啶-2-羰基)吡啶-2-基]-吡啶-2-基甲酮 以 甲醇 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Solvent-controlled generation of two pairs of mononuclear single-strand helical copper(II) complexes of 2,6-pyridinediylbis(2-pyridinyl)methanone: metal-promoted hydrolysis and solvolysis with asymmetric induction

  摘要：

  Two pairs of stable mononuclear single-strand helical complexes were obtained through controlled self-assembly using 2,6-pyridinediylbis(2-pyridinyl)methanone (L) and copper(II) salts. CuL(NO3)(2) (1) and [CuL'(H2O)](NO3)(2) (2) represent a pair in which L takes the diketo form in 1 but hydrolyzed in 2, while CuLCl2 (3) and [CuL''Cl]Cl (4) constitute another pair in which L remains intact in 3 but solvolyzed in 4. A mechanism of the metal-promoted hydrolysis and solvolysis of ligand L with asymmetric induction is proposed through studies on the crystal structures of these complexes. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.11.024