Iron and ruthenium triple-decker complexes with a central pentaphospholyl ligand
摘要:
Thirty-electron triple-decker complexes with a central pentaphospholyl ligand [(eta-C5Me5)Fe(mu-eta:eta-P-5)M(eta-C5R5)]BF4 (M = Fe, R = Me or M = Ru, R = H, Me) were synthesized by a stacking reaction of cationic 12-electron fragments [(eta-C5R5)M](+) with (eta-C5Me5)Fe(eta-P-5).
Iron- and Ruthenium-Containing Triple-Decker Complexes with a Central Pentaphospholyl Ligand − X-ray Structures of [(η-C5H5)Fe(μ-η:η-P5)Ru(η-C5Me5)]PF6 and [(η-C5Me5)Ru(μ-η:η-P5)Ru(η-C5Me5)]PF6
作者:Alexander R. Kudinov、Dmitry A. Loginov、Zoya A. Starikova、Pavel V. Petrovskii、Maddalena Corsini、Piero Zanello