monocesium monosodium mono(hexachloroscandate(III)) | 28015-76-1

• 英文名称: monocesium monosodium mono(hexachloroscandate(III))
• CAS: 28015-76-1
• 化学式: Cl₆Sc*2Cs*Na
• 分子量: 546.474
• InChiKey: DZSCJCRQXYHSRA-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  -1.86
• 重原子数：
  9.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  scandium(III) chloride hexahydrate 、 cesium chloride 、 sodium chloride 以 盐酸 为溶剂， 生成 monocesium monosodium mono(hexachloroscandate(III))
  参考文献：
  名称：

  Weaver, S. Catherine; McClure, Donald S., Inorganic Chemistry, 1992, vol. 31, # 13, p. 2814 - 2820

  摘要：

  DOI：

文献信息

• Changes of vibrational modes upon melting solid Cs2NaScCl6, Cs3ScCl6, Cs3Sc2Cl9 and ScCl3
  作者：G.D Zissi、G.N Papatheodorou

  DOI：10.1016/s0009-2614(99)00583-7

  日期：1999.7

  Raman spectra of Cs2NaScCl6, Cs3ScCl6, Cs3Sc2Cl9 and ScCl3 compounds have been measured from 25 degrees C to temperatures above their melting points. The vibrational modes of the discrete species ScCl63- and Sc2Cl93- in the solids are transferred upon melting into the liquid and participate in an equilibrium involving ScCl4-. The spectra of solid ScCl3 are dominated by the vibrational modes of a triple layer of ions consisting of edge-sharing ScCl63- octahedra. Two main bands are seen in the melt spectra which infer a molecular liquid but a rather complex melt structure is suggested by the overall physicochemical data. (C) 1999 Elsevier Science B.V. All rights reserved.