RhCl(P(C6H4-3-CF3)3)3 | 252654-98-1

• 英文名称: RhCl(P(C6H4-3-CF3)3)3
• CAS: 252654-98-1
• 化学式: C₆₃H₃₆ClF₂₇P₃Rh
• 分子量: 1537.22
• InChiKey: VFGBOGQLIAKVTA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(ethylene)rhodium(I) chloride dimer 、 tris(3-trifluoromethylphenyl)-phosphine 以 氘代氯仿 为溶剂， 生成 RhCl(P(C6H4-3-CF3)3)3
  参考文献：
  名称：

  Synthesis and coordination chemistry of meta-perfluoroalkyl-derivatised triarylphosphines

  摘要：

  The synthesis and coordination chemistry of the PPhx(C6H4-3-C6F13)(3-x) (x=0, 1, 2) ligands containing perfluoroalkyl ponytails have been investigated. A comparison of the spectroscopic data for coordination complexes containing these ligands with those for complexes containing PPh3 or the related para-derivatised triarylphosphines indicates that these meta-derivatised ligands are slightly poorer sigma-donors and that steric crowding in the [PtCl2L2] complexes results in the formation of the normally thermodynamically less-favourable trans-isomers. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00202-8