[2-(4-hydroxyphenylazo)phenyl]bis-(pentafluorophenyl)borane | 1361928-62-2

• 英文名称: [2-(4-hydroxyphenylazo)phenyl]bis-(pentafluorophenyl)borane
• CAS: 1361928-62-2
• 化学式: C₂₄H₉BF₁₀N₂O
• 分子量: 542.143
• InChiKey: OUKCTUKEBXLHJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [2-(4-hydroxyphenylazo)phenyl]bis-(pentafluorophenyl)borane 在 NaH 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 生成 2-(4-(3,3-bis(perfluorophenyl)-3H-2l4,3l4-benzo[d][1,2,3]diazaborol-2-yl)phenoxy)-N,N,N-trimethylethan-1-aminium iodide
  参考文献：
  名称：

  Synthesis and properties of water-soluble fluorescent 2-borylazobenzenes bearing ionic functional groups

  摘要：

  Water-soluble fluorescent azobenzenes have been synthesized by quaternization of 2-[bis(pentafluorophenyl) boryl] azobenzenes bearing dimethylamino groups with iodomethane or propanesultone. The 2-borylazobenzenes both dissolve and fluoresce in water. The double introduction of ionic moieties provides the azobenzenes with higher water solubility. Dynamic light scattering and scanning electron microscopy measurements indicate that the 2-borylazobenzenes aggregate in water. They are expected to be applied in aqueous environments. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.07.053
• 作为产物：
  描述：

  2-[bis(pentafluorophenyl)boryl]-4'-(tert-butyldimethylsiloxy)azobenzene 在 盐酸 作用下， 以 甲醇 、 水 为溶剂， 反应 15.0h， 以92%的产率得到[2-(4-hydroxyphenylazo)phenyl]bis-(pentafluorophenyl)borane
  参考文献：
  名称：

  Synthesis and properties of water-soluble fluorescent 2-borylazobenzenes bearing ionic functional groups

  摘要：

  Water-soluble fluorescent azobenzenes have been synthesized by quaternization of 2-[bis(pentafluorophenyl) boryl] azobenzenes bearing dimethylamino groups with iodomethane or propanesultone. The 2-borylazobenzenes both dissolve and fluoresce in water. The double introduction of ionic moieties provides the azobenzenes with higher water solubility. Dynamic light scattering and scanning electron microscopy measurements indicate that the 2-borylazobenzenes aggregate in water. They are expected to be applied in aqueous environments. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.07.053