AuCl(3-((diphenylphosphorothioyl)-methyl)-benzene-1,2-diole) | 1318239-80-3

• 英文名称: AuCl(3-((diphenylphosphorothioyl)-methyl)-benzene-1,2-diole)
• CAS: 1318239-80-3
• 化学式: C₁₉H₁₇AuClO₂PS
• 分子量: 572.802
• InChiKey: GUYQYWCVUUQGBL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 3-[(diphenylphosphorothioyl)-methyl]-benzene-1,2-diol 以 二氯甲烷 为溶剂， 以76%的产率得到AuCl(3-((diphenylphosphorothioyl)-methyl)-benzene-1,2-diole)
  参考文献：
  名称：

  Different coordination behavior of a catechol phosphine and its sulfide: Formation of an unprecedented dinuclear rhodium complex with a non-coordinated PS unit

  摘要：

  Sulfurization of 3-[(diphenylphosphinyl)methyl]benzene-1,2-diol 1 produced phosphine sulfide 3. Both ligands reacted easily to form gold(I) and rhodium(I) complexes which were characterized by analytical and spectroscopic data, and single-crystal X-ray diffraction studies. Whereas the phosphine prefers to form complexes with a metal-to-ligand ratio of 1:2 with both metals, the phosphine sulfide exhibits a reduced donor power and yields only a 1:1 complex with AuCl. With rhodium(I), formation of a homobimetallic complex with a metal-to-ligand ratio of 2:1 was found. This complex displays an unusual coordination of both metal atoms to the catechol moiety whereas the phosphine sulfide moiety remains inactive. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.076