cesium sulfamate | 124556-84-9

• 英文名称: cesium sulfamate
• 英文别名: cesium amidosulfonate；Cesium Amidosulfonat；cesium;sulfamate
• CAS: 124556-84-9
• 化学式: Cs*H₂NO₃S
• 分子量: 228.992
• InChiKey: HWKFJAMPPGRNEY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -4.59
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  91.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  cesium sulfamate 以 neat (no solvent) 为溶剂， 生成 cesium imidosulfonate
  参考文献：
  名称：

  Thermogravimetrische Untersuchung der thermischen Zersetzung von Amidosulfonaten einwertiger metalle

  摘要：

  The thermal decomposition of molten CsSO3NH2, NH4SO3NH2, RbSO3NH2, TISO3NH2, NaSO3NH2 and KSO3NH2 was studied by means of thermogravimetry. A different behaviour of decomposition of the K and Na salts on the one hand, and the other salts on the other, was found. While the decomposition of CsSO3NH2, NH4SO3NH2, RbSO3NH2 and TISO3NH2 starts immediately on reaching the experimental temperature, the decomposition of the Na and K amidosulfonates starts after an incubation time. The activation energies of thermal decomposition of the salts studied were determined. (C) 1997 Elsevier Science B.V.

  DOI：

  10.1016/s0040-6031(97)00256-6
• 作为产物：
  描述：

  氨基磺酸 、 caesium carbonate 以 水 为溶剂， 生成 cesium sulfamate
  参考文献：
  名称：

  Thermogravimetrische Untersuchung der thermischen Zersetzung von Amidosulfonaten einwertiger metalle

  摘要：

  The thermal decomposition of molten CsSO3NH2, NH4SO3NH2, RbSO3NH2, TISO3NH2, NaSO3NH2 and KSO3NH2 was studied by means of thermogravimetry. A different behaviour of decomposition of the K and Na salts on the one hand, and the other salts on the other, was found. While the decomposition of CsSO3NH2, NH4SO3NH2, RbSO3NH2 and TISO3NH2 starts immediately on reaching the experimental temperature, the decomposition of the Na and K amidosulfonates starts after an incubation time. The activation energies of thermal decomposition of the salts studied were determined. (C) 1997 Elsevier Science B.V.

  DOI：

  10.1016/s0040-6031(97)00256-6

文献信息

• Structural, spectral, thermal, micro hardness, dielectric and etching studies of third order nonlinear optical material Cesium Sulfamate
  作者：S. Rafi Ahamed、P. Srinivasan、J. Balaji、S. Gokul Raj、S. Mohan

  DOI：10.1016/j.jallcom.2017.01.158

  日期：2017.4

  Optically good quality single crystals of Cesium Sulfamate (CeS) were grown by slow evaporation technique. The grown crystals were characterized by various characterization techniques such as single crystal XRD, FT-IR, dielectric, TG/DTA, microhardness and Z-scan studies. Single crystal X-ray Diffraction analysis confirms that the crystal belongs to the monoclinic crystal system. The functional groups present in the crystal was identified by FT-IR analysis. Dielectric studies were measured for the crystal from 50 Hz to 5 MHz at room temperature. The thermal studies were performed to know the thermal behavior. Mechanical behavior of the crystal was measured using Vickers microhardness tester. The etching technique was used to study the dislocations in the single crystals. The nonlinear absorption coefficient beta), nonlinear refractive index (n(2)) and third harmonic generation studies were also carried out for the title crystal. (C) 2017 Elsevier B.V. All rights reserved.
• Parent, Yves, Bulletin de la Societe Chimique de France, 1982, vol. I, p. 284 - 288
  作者：Parent, Yves

  DOI：——

  日期：——