[Au(dipydido[f,h]quinoxaline)Cl2]Cl | 933036-78-3

• 英文名称: [Au(dipydido[f,h]quinoxaline)Cl2]Cl
• CAS: 933036-78-3
• 化学式: C₁₄H₈AuCl₂N₄*Cl
• 分子量: 535.57
• InChiKey: NAZMRJRBFPBBSR-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloroauric acid 、 吡嗪并[2，3-f]的[1，10]菲咯啉 以 水 、 乙腈 为溶剂， 以60%的产率得到[Au(dipydido[f,h]quinoxaline)Cl2]Cl
  参考文献：
  名称：

  Spectroscopic and electrochemical properties of dichlorodiimine complexes of Au(III) and Pt(II) with 1,4-diazine derivatives of o-phenanthroline

  摘要：

  A series of dichlorodiimine complexes [M(N boolean AND N)Cl-2](z) of Au(III) and Pt(II) with 1,4-derivatives of o-phenanthroline [(N boolean AND N) = o-phenanthroline (phen), dipyrido[f,h]quinoxaline (dpq), dipyrido[a,c]phenazine (dppz), 6,7-dicyanodipyrido[f,h]quinoxaline (dicnq)] were prepared and characterized by H-1 NMR, electronic absorption, and emission spectroscopy and by cyclic voltammetry. In all the complexes, the (3)(pi-pi*)-type transition is the spin-forbidden transition of the lowest energy, responsible for the luminescence. The longest wave bands in the absorption spectra of the Au(III) and Pd(II) complexes were assigned in accordance with the results of the electrochemical studies to the (1)(pi-d*)- and (1)(d-pi*)-type transitions, respectively.

  DOI：

  10.1134/s1070363206060016