dipalladiumtetrachlorobis(ethyldipyrrolylphosphine) | 221083-28-9

• 英文名称: dipalladiumtetrachlorobis(ethyldipyrrolylphosphine)
• CAS: 221083-28-9
• 化学式: C₂₀H₂₆Cl₄N₄P₂Pd₂
• 分子量: 739.053
• InChiKey: RCLCGNLGCNPODV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 ethyldipyrrolylphosphine 以 二氯甲烷 为溶剂， 以87%的产率得到dipalladiumtetrachlorobis(ethyldipyrrolylphosphine)
  参考文献：
  名称：

  Synthesis and X-ray crystal structure of dipalladiumtetrachlorobis(ethyldipyrrolylphosphine)

  摘要：

  The ligand ethyldipyrrolylphosphine and the corresponding palladium(II) complex, [PdCl{PEt(pyrrolyl)(2)}mu Cl](2), were synthesized. The X-ray single-crystal structure of this palladium complex was determined; it crystallizes in the monoclinic space group P2(1)/n with a = 15.347(7), b = 11.212(6), c = 17.355(5) Angstrom and beta = 115.72(3)degrees and contains a central pseudo square planar Pd2Cl4 ring having a trans conformation of N-pyrrolyl phosphines. The arrangement of the pyrrole substituents around the phosphorus atom in the complex clearly shows the inaccessibility of the alpha-carbon for polymerization. (C) 1999 Elsevier Science Ltd.

  DOI：

  10.1016/s0025-5408(98)00181-0