| 1063996-65-5

• CAS: 1063996-65-5
• 化学式: C₄₄H₅₀FeN₄O₂
• 分子量: 722.754
• InChiKey: QCGUTWIWFUWRKL-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 p-TsOH 、 HCl 作用下， 以 甲醇 、 水 为溶剂， 以43%的产率得到1,1'-bis(n-(3-methyl-5-phenyl-1H-pyrazol-4-yl)ethyl)ferrocene
  参考文献：
  名称：

  A Toluene Guest in a Poly(heteronuclear) Complex Host of Ferrocenyl−(CH₂)₂-Bridged Bis(pyrazole)

  摘要：

  Reactions of ferrocenyl-(CH2)(n)-bridged bis(pyrazoles) with nickelocene afforded inter- and intramolecular dimeric poly(heteronuclear) cyclopentadienylnickel(II) complexes com which a novel toluene-embodied guest-host system was obtained by pi-interaction. The present paper has demonstrated a new class of potentially useful organometallic building blocks for supramolecular assembly and the first example of a pyrazolato ligand exhibiting a charge transfer type pi-interaction.

  DOI：

  10.1021/om800704a
• 作为产物：
  描述：

  iron(II) chloride 、 在 n-C₄H₉Li 作用下， 以 四氢呋喃 为溶剂， 以61%的产率得到
  参考文献：
  名称：

  A Toluene Guest in a Poly(heteronuclear) Complex Host of Ferrocenyl−(CH₂)₂-Bridged Bis(pyrazole)

  摘要：

  Reactions of ferrocenyl-(CH2)(n)-bridged bis(pyrazoles) with nickelocene afforded inter- and intramolecular dimeric poly(heteronuclear) cyclopentadienylnickel(II) complexes com which a novel toluene-embodied guest-host system was obtained by pi-interaction. The present paper has demonstrated a new class of potentially useful organometallic building blocks for supramolecular assembly and the first example of a pyrazolato ligand exhibiting a charge transfer type pi-interaction.

  DOI：

  10.1021/om800704a