[iridium bis(7,8-benzoquinoline)(4,4-di-tert-butyl-2,2'-bipyridine)]hexafluorophosphate | 1345338-85-3

• 英文名称: [iridium bis(7,8-benzoquinoline)(4,4-di-tert-butyl-2,2'-bipyridine)]hexafluorophosphate
• CAS: 1345338-85-3
• 化学式: C₄₄H₄₀IrN₄*F₆P
• 分子量: 962.013
• InChiKey: ODKDUHMIWACYFE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 tetrakis(benzo[h]quinoline-C(10),N')(μ-dichloro)diiridium*C7H8 、 4,4'-二叔丁基-2,2'-二吡啶 以 乙二醇 为溶剂， 以70%的产率得到[iridium bis(7,8-benzoquinoline)(4,4-di-tert-butyl-2,2'-bipyridine)]hexafluorophosphate
  参考文献：
  名称：

  New iridium cyclometallated complexes with potential application in OLED

  摘要：

  The photophysical and electrochemical properties of cyclometallic cationic iridium complexes that also contain bipyridine type ligands have been investigated in this work. The effect on the photophysical properties of the complexes on the presence of aliphatic long chain or branched substitution was analyzed. The complexes show photoluminescence maxima in the green-blue region of the visible spectrum, with acceptable quantum yields and lifetime, showing in this way potentiality to be tested in OLED devices. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.08.010