| 186457-89-6

• CAS: 186457-89-6
• 化学式: C₁₂H₁₂CrO₄
• 分子量: 272.221
• InChiKey: RHBGYHWWVJIXTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 η6-(vinylbenzene)tricarbonylchromium(0) 在 KOH 作用下， 以 四氢呋喃 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  Regioselective Addition of Various Heteronucleophiles to (Styrene)Cr(CO)₃ Complexes

  摘要：

  (Styrene)Cr(CO)(3) complexes underwent the addition of various heteronucleophiles such as alcohols, amines, and thiols, in the presence of KOH, and the beta-addition products were selectively obtained in moderate to excellent yields. The structural details and features of the product complexes were also elucidated.

  DOI：

  10.1021/om200268v

文献信息

• Hydroboration, followed by water addition of benchrotrenic alkenes. Formal dihydrogen addition
  作者：Bertrand Caro、Marie-Claude Sénéchal-Tocquer、Denis Sénéchal、Françoise Robin-le Guen

  DOI：10.1016/s0022-328x(96)06329-2

  日期：1996.11

  The reaction of the BH3-THF reagent with benchrotrenic alkenes, followed by a water addition and the formation of hydrogenated products are described. This formation and the regioselectivity observed is a consequence of the electron withdrawing effect of the Cr(CO)3 group.

  描述了BH 3 -THF试剂与替丁烯属烯烃的反应，随后加水并形成氢化产物。观察到的这种形成和区域选择性是Cr（CO）3基团的电子吸收作用的结果。