(Cp*Rh[Se2C2(B10H10)])(Co2(CO)5) | 869499-01-4

• 英文名称: (Cp*Rh[Se2C2(B10H10)])(Co2(CO)5)
• CAS: 869499-01-4
• 化学式: C₁₇H₂₅B₁₀Co₂O₅RhSe₂
• 分子量: 796.304
• InChiKey: BDFKDLIELISTLX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dicobalt octacarbonyl 、 η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-diselenolato]rhodium 在 Me₃NO 作用下， 以 甲苯 为溶剂， 以82%的产率得到(Cp*Rh[Se2C2(B10H10)])(Co2(CO)5)
  参考文献：
  名称：

  Heteronuclear Tungsten and Cobalt Derivatives of the 16-Electron Half-Sandwich Complex Cp*Rh[E₂C₂(B₁₀H₁₀)] (E = S, Se)

  摘要：

  The 16-electron half-sandwich rhodium complex [Cp*Rh{E2C2(B10H10)}] [E = S (1a), Se (1b)] (Cp* = eta(5)-C5Me5) reacted with W(CO)(3)(py)(3) in the presence of BF3 center dot Et2O in THF solution to afford {Cp*Rh[E2C2(B10H10)]}(2)W(CO)(2) (E = S (2a); Se (2b)), (Cp*Rh)(2)[S2C2(B10H10)] (3), CP*Rh[S2C2(B10H10)]W(CO)(2)[S2C2(B10H10)] (4), and Cp*Rh(CO)[Se2C2(B10H10)]W(CO)(5) (5). The trinuclear clusters {Cp*Rh[E2C2(B10H10)}[CO2(CO)(5)] [E = S (6a), Se (6b)] were obtained from the reactions of 1a and 1b with CO2(CO)(8) in the presence of Me3NO. The complexes have been fully characterized by IR and NMR spectroscopy as well as by element analyses. The X-ray crystal structures of complexes 2-6 are reported.

  DOI：

  10.1021/om050598p