dichloro(1,4,8,11,15,18,22,25-octa(dodecylthio)phthalocyaninato)tin(IV) | 1092652-37-3

• 英文名称: dichloro(1,4,8,11,15,18,22,25-octa(dodecylthio)phthalocyaninato)tin(IV)
• CAS: 1092652-37-3
• 化学式: C₁₂₈H₂₀₈Cl₂N₈S₈Sn
• 分子量: 2305.26
• InChiKey: HJOMOVJJFZJENV-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  tin(ll) chloride 、 1,4,8,11,15,18,22,25-octa(dodecylthio)phthalocyanine 以 戊醇 为溶剂， 以80%的产率得到dichloro(1,4,8,11,15,18,22,25-octa(dodecylthio)phthalocyaninato)tin(IV)
  参考文献：
  名称：

  Synthesis, electrochemical characterization of tetra- and octa-substituted dodecyl-mercapto tin phthalocyanines in solution and as self-assembled monolayers

  摘要：

  Non-peripherally (alpha) tetra- (9) and octa-(7) substituted dodecyl-mercapto tin(IV) phthalocyanines were synthesized and their electrochemical behavior studied. Cyclic voltammetry and spectroelectrochemistry show ring-based reductions for 7 and 9, the former shows two ring oxidations, while the latter shows only one ring-based oxidation. The adsorption kinetics of (7) and (9) on gold electrode were investigated by electrochemical impedance spectroscopy (EIS). The equilibrium constant (K) for the adsorption and the Gibbs free energy (Delta G(ads)) of the SAMs were evaluated based on the Frumkin isotherm. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2008.08.018