(5-dimethylaminonaphthalene-1-sulfonylimido)bis(triphenylphosphino)digold(I) | 1321576-91-3

• 英文名称: (5-dimethylaminonaphthalene-1-sulfonylimido)bis(triphenylphosphino)digold(I)
• CAS: 1321576-91-3
• 化学式: C₄₈H₄₂Au₂N₂O₂P₂S
• 分子量: 1166.82
• InChiKey: POYWMZJPORFDHP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  triphenylphosphinegold(I) cation 、 (5-dimethylaminonaphthalene-1-sulfonylimido)bis(triphenylphosphino)digold(I) 、 lithium perchlorate 以 四氢呋喃 、 二氯甲烷 为溶剂， 生成 (5-dimethylaminonaphthalene-1-sulfonylimido)tris(triphenylphosphino)trigold(I) perchlorate
  参考文献：
  名称：

  Mono-, di-, and tri-nuclear gold(I) complexes with dansyl moiety: Synthesis, characterization, and photophysical properties

  摘要：

  Mono-, di-, and tri-nuclear gold(I) complexes with dansyl group (dansyl = 5-dimethylamino-naphthalene-1-sulfonyl), 1-3, have been synthesized and their photophysical properties investigated. The crystal structures of complexes 2 and 3 were determined by X-ray diffraction. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.05.041
• 作为产物：
  描述：

  potassium 5-dimethylaminonaphthalen-1-sulfanylamide 在 tBuOK 、 NaOCH₃ 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 生成 (5-dimethylaminonaphthalene-1-sulfonylimido)bis(triphenylphosphino)digold(I)
  参考文献：
  名称：

  Mono-, di-, and tri-nuclear gold(I) complexes with dansyl moiety: Synthesis, characterization, and photophysical properties

  摘要：

  Mono-, di-, and tri-nuclear gold(I) complexes with dansyl group (dansyl = 5-dimethylamino-naphthalene-1-sulfonyl), 1-3, have been synthesized and their photophysical properties investigated. The crystal structures of complexes 2 and 3 were determined by X-ray diffraction. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.05.041