(4,9-dimethyl-2-phenylbenz[f]indenyl)indenylzirconium dichloride | 852460-79-8

• 英文名称: (4,9-dimethyl-2-phenylbenz[f]indenyl)indenylzirconium dichloride
• CAS: 852460-79-8
• 化学式: C₃₀H₂₄Cl₂Zr
• 分子量: 546.651
• InChiKey: SIOZJOOZHXVVGQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  indenene zirconium trichloride 、 4,9-dimethyl-2-phenylbenz[f]indene 在 n-BuLi 作用下， 以 四氢呋喃 、 正己烷 、 甲苯 为溶剂， 以50%的产率得到(4,9-dimethyl-2-phenylbenz[f]indenyl)indenylzirconium dichloride
  参考文献：
  名称：

  Synthesis of zirconocenes bearing benz[f]indenyl ligand and their use as a catalyst in ethylene polymerization

  摘要：

  Benz[f]indenyl zirconium complexes have been successfully synthesized and characterized. Their catalytic activities were evaluated for the polymerization of ethylene. The complexes combined with MAO can be highly active single site catalysts, which display activities comparable with that of the Cp2ZrCl2/MAO system and provide very high molecular weight polyethylenes. The melting point of the polymers indicates the formation of linear polyethylene. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.02.008