chloro(1,4-bis(3-aminopropyl)piperazine)copper(II) perchlorate | 32104-12-4

• 英文名称: chloro(1,4-bis(3-aminopropyl)piperazine)copper(II) perchlorate
• CAS: 32104-12-4
• 化学式: C₁₀H₂₄ClCuN₄*ClO₄
• 分子量: 398.777
• InChiKey: BWJRMINJZOAPON-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,4-双(3-氨基丙基)哌嗪 、 copper(II) choride dihydrate 、 sodium perchlorate 以 水 为溶剂， 以75%的产率得到chloro(1,4-bis(3-aminopropyl)piperazine)copper(II) perchlorate
  参考文献：
  名称：

  Structure and characterization of non-cyclic tetraaza complexes of copper(II) and their reactions with nitric oxide

  摘要：

  [Cu(bapP)ClO4](+) (1) and [Cu(bapp)Cl](+) (2) were prepared by the reaction of 1,4-bis(3-aminopropyl)piperazine (bapp) with copper acetate and copper chloride in the presence of sodium perchlorate, respectively, and structurally characterized. Complex I has a square-pyramidal geometry, whereas [Cu(3,2,3-tet)(ClO4)](+) (A) has a polymeric octahedral geometry in its X-ray crystal structure. Complex I is stable against disproportionation, whereas complex A is unstable in the mono-valent Cu(l) state. An aqua ligand on complex I in aqueous solution is substituted by NO with kinetic constants of k(f) = 43 +/- 2 M-1 s(-1) and k(b) = (8.8 +/- 0.2) X 10(-2) s(-1) at 25 degreesC, whereas there were no spectral changes observed for complex A in saturated NO solution. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.02.019