Co(tris(2-(6-methypyridyl)methyl)amine)(tetrachlorocatechol-2H)(hexafluorophsophate) | 1071960-69-4

• 英文名称: Co(tris(2-(6-methypyridyl)methyl)amine)(tetrachlorocatechol-2H)(hexafluorophsophate)
• 英文别名: Co(Me3tpa)(TCCat)(PF6)
• CAS: 1071960-69-4
• 化学式: C₂₇H₂₄Cl₄CoN₄O₂*F₆P
• 分子量: 782.283
• InChiKey: YPNILJGVYXPIEK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 四氯邻苯二酚 、 tris[(6-methyl-2-pyridyl)methyl]amine 、 cobalt(II) chloride 在 triethylamine 、 AgNO₃ 作用下， 以 甲醇 为溶剂， 生成 Co(tris(2-(6-methypyridyl)methyl)amine)(tetrachlorocatechol-2H)(hexafluorophsophate)
  参考文献：
  名称：

  Thermodynamics of valence tautomeric interconversion in a tetrachlorodioxolene:cobalt 1:1 adduct

  摘要：

  We report here the X-ray structure, solid state magnetic properties and temperature dependent solution electronic spectra of a 1: 1 cobalt: tetrachlorodioxolene adduct. The study showed that in the solid state this system undergoes an intramolecular electron transfer above 300 K, passing from a Co(III)-Cat charge distribution to a Co(II)-SQ one (valence tautomeric interconversion). The occurrence of this process has also been evidenced in solution by the temperature dependent electronic spectra, showing the transition to take place around 250 K. This study also provided for the first time the thermodynamic parameters of the valence tautomeric process in a 1: 1 adduct, confirming its entropy driven character. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.02.044