[[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2(OHCHMe2)]BF4 | 503158-87-0

• 英文名称: [[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2(OHCHMe2)]BF4
• CAS: 503158-87-0
• 化学式: BF₄*C₃₀H₃₀NO₃Ru
• 分子量: 640.448
• InChiKey: GJIPYMVVQWHRMG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  异丙醇 、 [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl 、 silver tetrafluoroborate 以 二氯甲烷-D2 为溶剂， 生成 [[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2(OHCHMe2)]BF4
  参考文献：
  名称：

  Synthesis and Reactivity of Hydroxycyclopentadienyl and Aminocyclopentadienyl Ruthenium Alcohol Complexes

  摘要：

  Cationic aminocyclopentadienyl and hydroxycyclopentadienyl ruthenium alcohol complexes were synthesized from reaction of the corresponding ruthenium chloride with AgBF4 in the presence of an alcohol. Exchange rates of free alcohol with hydroxycyclopentadienyl and aminocyclopentadienyl ruthenium benzyl alcohol complexes were rapid (t(1/2) = 5-10 min) at -47 degreesC.

  DOI：

  10.1021/om020891e