trans-carbonyliodotris(triphenylstibine-κSb)rhodium(I) | 500572-58-7

• 英文名称: trans-carbonyliodotris(triphenylstibine-κSb)rhodium(I)
• CAS: 500572-58-7
• 化学式: C₅₅H₄₅IORhSb₃
• 分子量: 1317.02
• InChiKey: SPTKEYFVJBAMLI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三苯基锑 、 di(rhodium)tetracarbonyl dichloride 以 丙酮 为溶剂， 以80%的产率得到trans-carbonyliodotris(triphenylstibine-κSb)rhodium(I)
  参考文献：
  名称：

  trans-Carbonyliodotris(triphenylstibine-κSb)rhodium(I)

  摘要：

  The crystal structure of the title compound, [RhI(C18H15Sb)(3) (CO)], represents a rare example of a crystallographically characterized five-coordinate Rh-I-SbPh3 complex. The compound crystallizes with the I-Rh-CO core on a threefold rotation axis, with three crystallographically equivalent triphenylstibine ligands. Selected geometric parameters are: Rh-I = 2.7159 (8), RhDSb = 2.5962 (4), Rh-C-CO = 1.825 (6) and C-CO-O 1.153 (6) Angstrom, and Sb-Rh-I = 89.374 (10) and Sb-Rh-C-CO = 90.626 (10)degrees. The cone angle of the SbPh3 ligand was determined as 137degrees, according to the Tolman model.

  DOI：

  10.1107/s0108270102018747