Bromo(trichloro)boranuide | 36500-74-0

• 英文名称: Bromo(trichloro)boranuide
• CAS: 36500-74-0
• 化学式: BBrCl₃
• 分子量: 197.074
• InChiKey: FDHWAAFJFRFAPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.53
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  溴甲烷 、 三氯化硼 生成 Bromo(trichloro)boranuide
  参考文献：
  名称：

  在220-410 K的温度范围内与三氟化硼和三氯化硼进行卤化物离子反应时的辐射加三体加成

  摘要：

  DOI：

  10.1021/j100338a051

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.10, 4.4, page 214 - 216
  作者：

  DOI：——

  日期：——
• Mixed tetrahaloborate ions. Detection and study by nuclear magnetic resonance
  作者：J. S. Hartman、G. J. Schrobilgen

  DOI：10.1021/ic50111a005

  日期：1972.5
• Solids containing methylhalophosphonium cations [(CH3)n PX+4−n] (n = 1–3 XCl,Br): an investigation using magic-angle spinning NMR spectroscopy
  作者：Robin K. Harris、Andrew Root、Peter N. Gates、Alan S. Muir

  DOI：10.1016/0584-8539(92)80143-k

  日期：1992.10

  A selection of complexes containing [(CH3)nPX4-n+] cations (X = Cl, Br) have been investigated by magic-angle spinning (MAS) P-31 and B-11 NMR spectroscopy. Qualitative information about ionic motion in these systems is derived from the observed linewidths, which are dependent upon the nature of the anions present in the lattices. Isomers of [(CH3)PCl3+Cl-] and [(CH3)2PCl2+Cl-] are detected, confirming previous Raman spectroscopic observations. The mixed-halogen cations [(CH3)PCl2Br+], [(CH3)PClBr2+] and [(CH3)2PClBr+] are also observed, complexed with both single-halide and polyatomic anions. Differences in NMR linewidths are again noted. These results are compared with Raman studies on the same complexes and contrasted with a similar investigation of the [PClnBr4+-n] (0 less-than-or-equal-to n less-than-or-equal-to 4) system.