| 183197-87-7

• CAS: 183197-87-7；183387-17-9
• 化学式: C₄HCoO₄
• 分子量: 173.032
• InChiKey: KFQDAZBBZFLQPV-AOEZGMRWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dicobalt octacarbonyl 、 四乙二醇二甲醚 、 一氧化碳 、 硫酸 、 C13取代的一氧化碳 以 吡啶 为溶剂， 生成
  参考文献：
  名称：

  Microwave measurements of the gas‐phase molecular structure of cobalt tetracarbonyl hydride

  摘要：

  Microwave rotational spectra for six isotopomers of HCo(CO)4 were measured using a Flygare–Balle type spectrometer. Transitions were measured in the 4–10 GHz range. The data were analyzed to obtain rotational constants, 59Co quadrupole coupling strengths, distortion constants and spin–rotation interaction strengths. The common isotopomer is clearly a symmetric top, with C3v symmetry. For the common isotopomer B=1131.7212(9) MHz and eQq(59Co)=116.62(3) MHz. The rotational constants were used to determine the complete, three-dimensional structure of this complex. The measured H–Co bond length of 1.52(2) Å is significantly shorter than the previous value from electron diffraction work. Other structural parameters for this complex are reported and discussed.

  DOI：

  10.1063/1.472216