| 698392-38-0

• CAS: 698392-38-0
• 化学式: C₁₇H₂₉I₂O₃Tm
• 分子量: 704.159
• InChiKey: QJXWZMHNENCUKH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 TmI2(thf)5 、 环戊二烯 以 四氢呋喃 为溶剂， 以21%的产率得到
  参考文献：
  名称：

  摘要：

  The reactions of LnI(2) (Ln = Nd (1) or Dy (2)) with cyclopentadiene (CpH) in THF at 0 degreesC afforded the CpLnI(2)(THF)(3) complexes in 65-67% yields. The reaction of thulium diiodide (3) with an excess of CpH at 60 degreesC produced CpTmI2(THF)(3), Cp2TmI(THF)(2), and TmI3(THF)(3) in 21, 58, and 63% yields, respectively. The reactions of 1 and 2 with pentamethyl-cyclopentadiene (Cp*H) in THF were accompanied by disproportionation giving rise to the CP*(2)LnI(THF)(2) and LnI(3)(THF)(x) complexes. Neodymium triiodide was isolated in the ionic form [NdI2(THF)(5)](+)[NdI4(THF)(2)](-). Its structure and the structure of CpTmI2(THF)(3) were established by X-ray diffraction analysis.

  DOI：

  10.1023/a:1026132017155