(η⁵-C5H5)(1,2-bis(diphenylphosphino)ethane)FeGaCl₂ | 1418880-45-1

• 英文名称: (η⁵-C5H5)(1,2-bis(diphenylphosphino)ethane)FeGaCl₂
• 英文别名: Cp(dppe)FeGaCl₂
• CAS: 1418880-45-1
• 化学式: C₃₁H₂₉Cl₂FeGaP₂
• 分子量: 659.995
• InChiKey: MEKIHIHXDKJNNC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dipotassium tetracarbonylferrate 、 (η⁵-C5H5)(1,2-bis(diphenylphosphino)ethane)FeGaCl₂ 以 四氢呋喃 为溶剂， 反应 5.0h， 以84%的产率得到(η⁵-C5H5)(1,2-bis(diphenylphosphino)ethane)FeGaFe(CO)₄
  参考文献：
  名称：

  Photoinduced Formal Gallylene Transfer from Gallium-Bridged Dimetallic Complexes to 16-Electron Metal Fragments

  摘要：

  Photoirradiation of the mixtures of Cp'(dppe)FeGaM(CO)(5) (Cp' = eta(5)-C5Me5 (Cp*), M = W (2), Cr (3); Cp' = eta(5)-C5H5 (Cp), M = W (5), Cr (6)) and Fe(CO)(5) in C6D6 caused formal gallylene transfer from 2, 3, 5, and 6 to the Fe(CO)(4) fragment to afford the gallium-bridged diiron complexes Cp'(dppe)FeGaFe(CO)(4) (Cp' = Cp* (1), Cp (4)) in moderate yields. Gallylene transfers with Cp(dppe)FeGaFe(CO)(4) (4) and M(CO)(6) (M = W, Cr) also took place to produce 5 and 6, respectively; however, that with Cp*(dppe)FeGaFe(CO)(4) (1) and M(CO)(6) did not proceed. Photoirradiation of 4 alone in toluene caused CO dissociation and dimerization to afford the gallylene-bridged tetrametallic complex {mu-Cp(dppe)FeGa}(2)Fe-2(CO)(6)(mu-CO) (8). In contrast to 4, the Cp* analogue 1 gave no gallylene-bridged complex in a similar reaction.

  DOI：

  10.1021/om301148y
• 作为产物：
  描述：

  [(CpFe(CO)2)GaCl2]n 、 1,2-双(二苯基膦)乙烷 以 甲苯 为溶剂， 反应 25.0h， 以64%的产率得到(η⁵-C5H5)(1,2-bis(diphenylphosphino)ethane)FeGaCl₂
  参考文献：
  名称：

  Photoinduced Formal Gallylene Transfer from Gallium-Bridged Dimetallic Complexes to 16-Electron Metal Fragments

  摘要：

  Photoirradiation of the mixtures of Cp'(dppe)FeGaM(CO)(5) (Cp' = eta(5)-C5Me5 (Cp*), M = W (2), Cr (3); Cp' = eta(5)-C5H5 (Cp), M = W (5), Cr (6)) and Fe(CO)(5) in C6D6 caused formal gallylene transfer from 2, 3, 5, and 6 to the Fe(CO)(4) fragment to afford the gallium-bridged diiron complexes Cp'(dppe)FeGaFe(CO)(4) (Cp' = Cp* (1), Cp (4)) in moderate yields. Gallylene transfers with Cp(dppe)FeGaFe(CO)(4) (4) and M(CO)(6) (M = W, Cr) also took place to produce 5 and 6, respectively; however, that with Cp*(dppe)FeGaFe(CO)(4) (1) and M(CO)(6) did not proceed. Photoirradiation of 4 alone in toluene caused CO dissociation and dimerization to afford the gallylene-bridged tetrametallic complex {mu-Cp(dppe)FeGa}(2)Fe-2(CO)(6)(mu-CO) (8). In contrast to 4, the Cp* analogue 1 gave no gallylene-bridged complex in a similar reaction.

  DOI：

  10.1021/om301148y