[(TpiPr2)Y]3(μ-O)2(μ-H)(μ-O-CH2-CH=CH2) | 1204325-57-4

• 英文名称: [(TpiPr2)Y]3(μ-O)2(μ-H)(μ-O-CH2-CH=CH2)
• 英文别名: ((κ3-hydridotris(3,5-diisopropyl-1-pyrazolyl)borate)Y)3HO2([(13)C3]propenolate)；(Tp(iPr2))3Y3HO2(O(13)CH2(13)CH(13)CH2)
• CAS: 1204325-57-4
• 化学式: C₈₄H₁₄₄B₃N₁₈O₃Y₃
• 分子量: 1756.3
• InChiKey: JLKVRNFBKQIGNS-QHDZMCRHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(TpiPr2)Y]3(μ-O)2(μ-H)(μ-O-CH2-CH=CH2) 以 氘代苯 为溶剂， 反应 12.0h， 生成 ¹³C₃-propene
  参考文献：
  名称：

  Synthesis and Reaction of [(Tp^iPr₂)LnH₂]₃ (Ln = Y, Lu) with CO: Trinuclear Cluster-Bound Propenolate en Route to Selective Formation of Propene

  摘要：

  The use of the Tp(iPr2) ligand led to the straightforward and high-yield synthesis of rare examples of trinuclear monoligand lanthanide dihydrides, [(Tp(2)(iPr))LnH(2)](3) (Ln = Y, Lu). The Y complex was found to mediate the hydrogenation and coupling of carbon monoxide with exclusive formation of propene via the intermediacy of a cluster-bound propenolate ligand.

  DOI：

  10.1021/ja905679k
• 作为产物：
  描述：

  ((κ3-hydridotris(3,5-diisopropyl-1-pyrazolyl)borate)Y)3(μ3-H)(μ2-H)5 、 C13取代的一氧化碳 以 pentane 为溶剂， 以78%的产率得到[(TpiPr2)Y]3(μ-O)2(μ-H)(μ-O-CH2-CH=CH2)
  参考文献：
  名称：

  Synthesis and Reaction of [(Tp^iPr₂)LnH₂]₃ (Ln = Y, Lu) with CO: Trinuclear Cluster-Bound Propenolate en Route to Selective Formation of Propene

  摘要：

  The use of the Tp(iPr2) ligand led to the straightforward and high-yield synthesis of rare examples of trinuclear monoligand lanthanide dihydrides, [(Tp(2)(iPr))LnH(2)](3) (Ln = Y, Lu). The Y complex was found to mediate the hydrogenation and coupling of carbon monoxide with exclusive formation of propene via the intermediacy of a cluster-bound propenolate ligand.

  DOI：

  10.1021/ja905679k