| 773155-97-8

• CAS: 773155-97-8
• 化学式: AlCl₄*C₁₂H₁₈AlN₂O
• 分子量: 402.063
• InChiKey: KOCSQWTZZQOLBN-ARACNKMWSA-I

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氧气 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Simple Generation of Cationic Aluminum Alkyls and Alkoxides Based on the Pendant Arm Tridentate Schiff Base

  摘要：

  The prepared in situ methyl(chloro)aluminum complex (2) from Me(2)AD and the pendant arm tridentate Schiff base (H-SchNMe(2)) was used to generate the methylaluminum cationic species [(SchNMe(2))AIMe](+) in further reaction with 1 equiv of AICI(3) or NaBPh4 as the chloride abstracting reagents. The exposure of the resulting methylaluminum cationic species to an excess of dry dioxygen at 0 degreesC afforded the alkoxyaluminum cationic species, [(SchNMe(2))AIOMe](+) or [(SchNMe(2))AIOPh](+). The alkoxylaluminum cations proved to be a very efficient catalyst in the polymerization of 6-caprolactone.

  DOI：

  10.1021/ic049337i
• 作为产物：
  描述：

  三氯化铝 、 二甲基氯化铝 、 (2-[1-(2-dimethylaminoethylimino)methyl]phenol) 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Simple Generation of Cationic Aluminum Alkyls and Alkoxides Based on the Pendant Arm Tridentate Schiff Base

  摘要：

  The prepared in situ methyl(chloro)aluminum complex (2) from Me(2)AD and the pendant arm tridentate Schiff base (H-SchNMe(2)) was used to generate the methylaluminum cationic species [(SchNMe(2))AIMe](+) in further reaction with 1 equiv of AICI(3) or NaBPh4 as the chloride abstracting reagents. The exposure of the resulting methylaluminum cationic species to an excess of dry dioxygen at 0 degreesC afforded the alkoxyaluminum cationic species, [(SchNMe(2))AIOMe](+) or [(SchNMe(2))AIOPh](+). The alkoxylaluminum cations proved to be a very efficient catalyst in the polymerization of 6-caprolactone.

  DOI：

  10.1021/ic049337i