trans-bis(triphenylantimony)chloro(N,N-dimethylaminobenzyl-C(1))palladium(II) | 713144-41-3

• 英文名称: trans-bis(triphenylantimony)chloro(N,N-dimethylaminobenzyl-C(1))palladium(II)
• 英文别名: trans-[PdCl(dmba)(SbPh3)2]
• CAS: 713144-41-3
• 化学式: C₄₅H₄₂ClNPdSb₂
• 分子量: 982.208
• InChiKey: LQUGEQOQNVFRCE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N-二甲基苄胺 以 甲醇 、 二氯甲烷 为溶剂， 生成 trans-bis(triphenylantimony)chloro(N,N-dimethylaminobenzyl-C(1))palladium(II)
  参考文献：
  名称：

  The synthesis and Crystal Structures of di-μ-dichloro-bis{[N,N-dimethylaminobenzyl-C1,N]dipalladium(II)} and of the Cocrystals of {chloro-(triphenylphosphino)-bis[N,N-dimethylaminobenzyl-C1,N]palladium(II)} and {trans-bis(triphenylphosphino)-chloro-[N,N-dimethylaminobenzyl-C]palladium(II)}

  摘要：

  The X-ray crystal structures of cyclopalladated complexes are reported. Reaction of {[Pd(dmba)(mu-Cl)](2)}, (1), (dmba = N(CH3)(2)-CH2C6H5) with triphenylphosphine gave crystals containing {chloro-(triphenylphosphino)-bis[N,N-dimethylaminobenzyl-C-1,N] palladium(II)} (2a) and {trans-bis(triphenylphosphino)-chloro-[N,N-dimethylaminozyl-C]palladium(II)} (2b). Complex (1) crystallises in the space group P2(1)/c with a = 7.849(l) Angstrom, b = 15.635(3) Angstrom, c = 8.352(l) Angstrom, beta = 109.29degrees, and D-calc = 1.895 g cm(-3) for Z = 2. Complexes (2a) and (2b) crystallize together in the space group P2(1)/n with a = 9.964(2) Angstrom, b = 34.228(5) Angstrom, c = 18.127(3) Angstrom, beta = 91.91 degrees, and D-calc = 1.439 g cm(-3). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2004.03.010