[(gold(I)chloride)4(5,11,17,23-tetrakis(butylthiomethyl)-25,26,27,28-tetrapropoxycalix[4]arene)] | 1156392-34-5

• 英文名称: [(gold(I)chloride)4(5,11,17,23-tetrakis(butylthiomethyl)-25,26,27,28-tetrapropoxycalix[4]arene)]
• CAS: 1156392-34-5
• 化学式: C₆₀H₈₈Au₄Cl₄O₄S₄
• 分子量: 1931.3
• InChiKey: HQFYUZAQSKPREG-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯(二甲基硫化)金(I) 、 5,11,17,23-tetrakis(butylthiomethyl)-25,26,27,28-tetrapropoxycalix[4]arene 以 丙酮 、 苯 为溶剂， 以71.2%的产率得到[(gold(I)chloride)4(5,11,17,23-tetrakis(butylthiomethyl)-25,26,27,28-tetrapropoxycalix[4]arene)]
  参考文献：
  名称：

  Pd(II) and Au(I) chloride complexes with tetrakis(butylthiomethyl)calix[4]arene: Synthesis and crystal structures

  摘要：

  Two novel complexes, (AuCl)(4)L-3 (I) and (PdCl2)(2)L-3 (II) (L-3 is calix[4]arene-thioether), were synthesized and their structures were determined. In complex I, one thioether group of molecule L-3 is coordinated to every Au atom. In complex II, the bidentate coordination of L-3 to the Pd atoms is observed; two thioether groups are in the trans-positions in the Pd square surrounding. Both complexes have the layered crystal lattices. In the Au complex, the layers are more stable due to the short contacts Au-Au (3.19-3.23 angstrom).

  DOI：

  10.1134/s1070328408050084