μ-chloro-μ-mesitylthiolatobis[(N,N-dimethylnaphthalamine-2C,N)]dipalladium(II) | 1040375-94-7

• 英文名称: μ-chloro-μ-mesitylthiolatobis[(N,N-dimethylnaphthalamine-2C,N)]dipalladium(II)
• 英文别名: sym-cis-[Pd2(μ-Cl)(μ-SMes)(C10H6CH2NMe2-C,N(-H))2]
• CAS: 1040375-94-7
• 化学式: C₃₃H₃₅ClN₂Pd₂S
• 分子量: 740.013
• InChiKey: TWNSZTWTDSCTQS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium 2,4,6-trimethylbenzenethiolate 以 甲醇 、 苯 为溶剂， 生成 μ-chloro-μ-mesitylthiolatobis[(N,N-dimethylnaphthalamine-2C,N)]dipalladium(II)
  参考文献：
  名称：

  Chalcogenolato-bridged cyclometallated binuclear palladium complexes: Synthesis, spectroscopy, structures of [Pd2(μ-Cl)(μ-SMes)(C10H6NMe2–C,N)2] and [Pd2(μ-SePh)2(C10H6NMe2–C,N)2]

  摘要：

  Reactions of orthometallated binuclear palladium complexes with NaER, obtained by NaBH(4) reduction of R(2)E(2) in methanol, gave complexes, [Pd(2)(mu-ER)(2)(C(boolean AND)Y)(2)] (HC(boolean AND)Y= N,N-dimethylbenzylamine (C(6)H(5)CH(2)NMe(2)), N,N-dimethylnaphthylamine (C(10)H(7)NMe(2)), tri-o-tolylphosphine {P(tol-o)(3)}; ER= SePh, SeMes, TePh, TeMes (Mes = 2,4,6-Me(3)C(6)H(2)). Similar reactions of [Pd(2)(mu-Cl)(2)(C(10)H(6)NMe(2)-C, N)(2)] with Pb(SMes)(2) or MesSH in the presence of NaHCO(3) gave chloro/thiolato-bridged complex [Pd(2)(mu-Cl)(mu-SMes)(C(10)H(6)NMe(2)-C, N)(2)]. The newly synthesized complexes were characterized by elemental analysis, UV-Vis, IR, NMR ((1)H, (13)C, (31)P, (77)Se, (125)Te) spectroscopy. These complexes crystallized out preferentially in sym-cis configuration. A low energy charge transfer transition has been identified from chalcogenolate centers to an empty pi* orbital of cyclometallated ligand in absorption spectroscopy in these complexes. The structures of [Pd(2)(mu-Cl)(mu-SMes)(C(10)H(6)NMe(2)-C, N)(2)] (1) and [Pd(2)(mu-SePh)(2)(C(10)H(6)NMe(2)-C, N)(2)] (3) have been established by single crystal X-ray diffraction analyses. In the former, the two palladium atoms are held together by chloro and thiolato bridges whereas in the latter, the two phenylselenolato ligands bridge two palladium atoms. The pyrolysis of [Pd(mu-TeMes)(C(10)H(6)NMe(2)-C, N)](2) (10) in a furnace gave Pd(7)Te(3) whereas thermolysis in TOPO afforded primarily PdTe(2). (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.01.005