trans-[RuCl2(8-hydroxy-7-quinolinecarboxaldehyde(1-))(1,10-phenathroline)]*H2O | 497153-36-3

• 英文名称: trans-[RuCl2(8-hydroxy-7-quinolinecarboxaldehyde(1-))(1,10-phenathroline)]*H2O
• CAS: 497153-36-3
• 化学式: C₂₂H₁₄Cl₂N₃O₂Ru*H₂O
• 分子量: 542.363
• InChiKey: UTEICWMWQNAGGO-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[RuCl2(8-hydroxy-7-quinolinecarboxaldehyde(1-))(1,10-phenathroline)]*H2O 以 neat (no solvent) 为溶剂， 生成 ruthenium(III) oxide
  参考文献：
  名称：

  Stereochemistry of new nitrogen containing heterocyclic aldehyde. VIII. Spectral and coordination modes of mixed-ligand of novel ruthenium(III) complexes

  摘要：

  Reaction of 8-hydroxy-7-quinolinecarboxaldehyde (LH) with RuCl3.XH2O afforded the compounds [RuL3] and/or [RuL2ClOH2]. Reactions of LH with RuCl3.XH2O in the presence of N-heterocyclic bases led to the formation of complexes of type [RuL2.ClPy] and [RuLCl2(o-Phen)] (Py = pyridine or o-Phen = 1,10-phenanthroline). The amine exchange reactions of coordinated Schiff bases in these complexes have been also carried out which give symmetrical tetradentate Schiff base complexes. These complexes were characterized by a combination of elemental analysis, IR, magnetic susceptibility measurements, H-1, C-13 NMR and electronic spectral analysis methods. The spectral data were utilized to compute the important ligand field parameters B, beta and Dq. Electronic spectra show all complexes are octahedral. The B-values suggest a strong covalency in the metal-ligand sigma-bond and the Dq-values indicate a medium-strong ligand field. The stereochemistry and the nature of the complexes are markedly dependent upon the molar ratios of the reactants, the pH of the system and the nature of the anions involved. The ligands behave as bi-(0,0) and tetradentate (N-2,O-2) donors. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(02)00082-3
• 作为产物：
  描述：

  1,10-菲罗啉 、 水合三氯化钌 、 水 、 8-羟基-7-喹啉甲醛 以 乙醇 、 水 为溶剂， 生成 trans-[RuCl2(8-hydroxy-7-quinolinecarboxaldehyde(1-))(1,10-phenathroline)]*H2O
  参考文献：
  名称：

  Stereochemistry of new nitrogen containing heterocyclic aldehyde. VIII. Spectral and coordination modes of mixed-ligand of novel ruthenium(III) complexes

  摘要：

  Reaction of 8-hydroxy-7-quinolinecarboxaldehyde (LH) with RuCl3.XH2O afforded the compounds [RuL3] and/or [RuL2ClOH2]. Reactions of LH with RuCl3.XH2O in the presence of N-heterocyclic bases led to the formation of complexes of type [RuL2.ClPy] and [RuLCl2(o-Phen)] (Py = pyridine or o-Phen = 1,10-phenanthroline). The amine exchange reactions of coordinated Schiff bases in these complexes have been also carried out which give symmetrical tetradentate Schiff base complexes. These complexes were characterized by a combination of elemental analysis, IR, magnetic susceptibility measurements, H-1, C-13 NMR and electronic spectral analysis methods. The spectral data were utilized to compute the important ligand field parameters B, beta and Dq. Electronic spectra show all complexes are octahedral. The B-values suggest a strong covalency in the metal-ligand sigma-bond and the Dq-values indicate a medium-strong ligand field. The stereochemistry and the nature of the complexes are markedly dependent upon the molar ratios of the reactants, the pH of the system and the nature of the anions involved. The ligands behave as bi-(0,0) and tetradentate (N-2,O-2) donors. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(02)00082-3