| 208038-16-8

• CAS: 208038-16-8
• 化学式: C₁₄H₁₉AlN₄
• 分子量: 270.313
• InChiKey: YBGFRZPNGNLOQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡咯 、 tris(dimethylamido)aluminum(III) dimer 以 正己烷 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Azido and amido derivatives of aluminium(III)

  摘要：

  The piperidinyl-substituted aluminium azide, [(pip)(2)AlN3](2) (5) (pip = piperidinyl, N(CH2)(4)CH2), has been synthesised via the reaction between [(pip)(2)AlCl](2) and one equivalent of NaN3. A related pyrrolyl derivative, [(Me2N(H))Al(pyr)(3)] (7) (pyr = pyrrolyl, N(CH)(3)CH), was prepared via the dimethylamine elimination reaction between [Al-2(NMe2)(6)] and six equivalents of pyrrole. A third aluminium amido complex, [Li(Al((NHBu)-Bu-t)(4))](2) (9), has been isolated from the salt elimination reaction between AlCl3 and an excess of (LiNHBu)-Bu-t. all three compounds have been characterised by X-ray crystallography; compounds 5 and 9 are dimeric in the solid state, whereas 7 is monomeric. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00207-6