[osmium(2,2'-bipyridine)2(3-(pyrrol-1-yl-methyl)pyridine)Cl]PF6 | 1024934-58-4

• 英文名称: [osmium(2,2'-bipyridine)2(3-(pyrrol-1-yl-methyl)pyridine)Cl]PF6
• CAS: 1024934-58-4
• 化学式: C₃₀H₂₆ClN₆Os*F₆P
• 分子量: 841.194
• InChiKey: QFDJCTJNFVSPLB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 锇二(2,2'-联吡啶)氯化物 、 3-(吡咯-1-甲基)吡啶 以 乙二醇 为溶剂， 以93%的产率得到[osmium(2,2'-bipyridine)2(3-(pyrrol-1-yl-methyl)pyridine)Cl]PF6
  参考文献：
  名称：

  Electrochemical studies of osmium-(pyrrole-methyl) pyridine-co-polymers deposited using the membrane template method

  摘要：

  The electrochemical characterisation of films formed by co-polymerisation of [Os(2,2'-bipyridin)(2)XCl] (Os-PMP) where X is 3-(pyrrole-lyl-methyl)pyridine with 3-methyl thiophene or 1,2-diaminobenzene was carried out. The use of the membrane template method, which allowed growth of tubules of redox co-polymer was employed in the case of 1,2-diaminobenzene. Cyclic voltammetry allowed formation of the most stable 3-methylthiophene/Os-PMP films while chronocoulometry was used to co-polymerise Os-PMP with 1,2-diaminobenzene, resulting in stable films of co-polymer micro-tubules with thin-film behaviour up to 0.5 V s(-1) (r(2) = 0.9997). Surface analysis was carried out using SEM. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2008.01.049