[Rh(CNC6H3(CH3)2-2,6)2(2,2'-bipyridine)][BF4] | 1160652-85-6

• 英文名称: [Rh(CNC6H3(CH3)2-2,6)2(2,2'-bipyridine)][BF4]
• 英文别名: [Rh(2,2'-bipyridine)(CNC6H3Me2-2,6)2]BF4
• CAS: 1160652-85-6
• 化学式: BF₄*C₂₈H₂₆N₄Rh
• 分子量: 608.251
• InChiKey: DCIPEUFCYHDFLE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [rhodium(I)(1,5-cyclooctadiene)(2,2'-bipyridine)](BF4) 、 2,6-二甲基苯基异腈 以 四氢呋喃 为溶剂， 以54%的产率得到[Rh(CNC6H3(CH3)2-2,6)2(2,2'-bipyridine)][BF4]
  参考文献：
  名称：

  Aggregation and DNA Intercalation Properties of Di(isocyano) Rhodium(I) Diimine Complexes

  摘要：

  A series of di(isocyano) rhodium(I) diimine complexes has been synthesized and characterized. Owing to the aggregation affinity of these complexes, they were found to exhibit thermochromism. To provide further insights into the aggregation affinity of these complexes, the enthalpy (Delta H) and entropy (Delta S) changes of dirnerizations of some of the complexes have been determined. In addition, the DNA intercalation properties of these complexes have also been investigated by the DNA unwinding assay.

  DOI：

  10.1021/om200723j

文献信息

• Thermochromic and Aggregation Properties of Bis(phenylisocyano) Rhodium(I) Diimine Complexes
  作者：Larry Tso-Lun Lo、Chi-On Ng、Hua Feng、Chi-Chiu Ko

  DOI：10.1021/om900161f

  日期：2009.7.13

  A series of bis(phenylisocyano) rhodium(I) diimine complexes with thermally mediated aggregation properties have beet? synthesized, and their photophysical and thermochronic properties have been studied.