[Ru8H4(CO)18(η(6)-C16H16)] | 164797-88-0

• 英文名称: [Ru8H4(CO)18(η(6)-C16H16)]
• CAS: 164797-88-0
• 化学式: C₃₄H₂₀O₁₈Ru₈
• 分子量: 1525.08
• InChiKey: LVCMHVBKXBMEGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Ru8H4(CO)18(η(6)-C16H16)] 在 CO 作用下， 以 二氯甲烷 为溶剂， 以30%的产率得到十二羰基三钌
  参考文献：
  名称：

  Preparation, characterisation, molecular and crystal structure of the octaruthenium arene clusters [Ru₈H₄(CO)₁₈(η⁶-arene)](arene = C₆H₆or C₁₆H₁₆)

  摘要：

  Two octaruthenium arene clusters, [Ru8H4(CO)(18)(eta(6)-arene)] (arene = C6H6 1 or C16H16 2), have been isolated from the thermolysis of [Ru-3(CO)(12)] in octane, in the presence of cyclohexene (C6H10) or [2.2] paracyclophane (C16H16), respectively. Both compounds 1 and 2 have been characterised in the solid state by single-crystal X-ray diffraction and their molecular and crystal structures determined. The reaction of 2 with CO resulted in conversion to the carbido cluster [Ru6C(CO)(14)(mu 3 eta(2):eta(2):eta(2)-C16H16)] and [Ru-3(CO)(12)] in quantitative amounts. Compound 1 did not react in the same way but yielded both [Ru4H4(CO)(12)] and [Ru4H2(CO)(13)].

  DOI：

  10.1039/dt9950000909
• 作为产物：
  描述：

  十二羰基三钌 、 对二甲苯二聚体 以 正辛烷 为溶剂， 以3%的产率得到[Ru8H4(CO)18(η(6)-C16H16)]
  参考文献：
  名称：

  Preparation, characterisation, molecular and crystal structure of the octaruthenium arene clusters [Ru₈H₄(CO)₁₈(η⁶-arene)](arene = C₆H₆or C₁₆H₁₆)

  摘要：

  Two octaruthenium arene clusters, [Ru8H4(CO)(18)(eta(6)-arene)] (arene = C6H6 1 or C16H16 2), have been isolated from the thermolysis of [Ru-3(CO)(12)] in octane, in the presence of cyclohexene (C6H10) or [2.2] paracyclophane (C16H16), respectively. Both compounds 1 and 2 have been characterised in the solid state by single-crystal X-ray diffraction and their molecular and crystal structures determined. The reaction of 2 with CO resulted in conversion to the carbido cluster [Ru6C(CO)(14)(mu 3 eta(2):eta(2):eta(2)-C16H16)] and [Ru-3(CO)(12)] in quantitative amounts. Compound 1 did not react in the same way but yielded both [Ru4H4(CO)(12)] and [Ru4H2(CO)(13)].

  DOI：

  10.1039/dt9950000909