di(μ-O(phenoxy))-bis(nitrato-2-[2-(hydroxyethylimino)-methyl]-phenoloimidazolecopper) | 805233-12-9

• 英文名称: di(μ-O(phenoxy))-bis(nitrato-2-[2-(hydroxyethylimino)-methyl]-phenoloimidazolecopper)
• CAS: 805233-12-9
• 化学式: C₂₄H₂₈Cu₂N₈O₁₀
• 分子量: 715.626
• InChiKey: RPSRGPQFKCNZAF-YINHMMFWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  咪唑 、 以 乙醇 为溶剂， 以68%的产率得到di(μ-O(phenoxy))-bis(nitrato-2-[2-(hydroxyethylimino)-methyl]-phenoloimidazolecopper)
  参考文献：
  名称：

  Synthesis and Structure of Di( -O_phenoxy)-bis{nitrato-2-[2-(hydroxyethylimino)-methyl]-phenoloimidazolecopper}

  摘要：

  The crystal structure of di(mu-O-phenoxy)-bis{nitrato-2-[2-(hydroxyethylimino)-methyl]-phenoloimidazolecopper} was determined. The crystals are monoclinic: a = 10.222(2) Angstrom, b = 13.810(3) Angstrom, c = 10.620(2) Angstrom, beta =103.67(3)degrees, space group P2(1)/n, Z = 2, R = 0.050. The copper atom coordinates the singly deprotonated 2[2-(hydroxyethylimino)-methyl]-phenol molecule, imidazole, and nitrate ion. The coordination polyhedron of the central atom is an extended tetragonal bipyramid with imine and imidazole nitrogen atoms and phenol and alcohol oxygen atoms lying in its base. One axial vertex of the bipyramid is occupied by the oxygen atom of the nitrato group and the other vertex, by phenol oxygen atom of the neighboring complex joined with the initial complex by the symmetry center. Two bridging phenol oxygen atoms unite the complexes into a centrosymmetrical dimer.

  DOI：

  10.1023/b:ruco.0000034789.69533.9a