[nickel(II)]3(2-[(2-isopropylaminoethylimino)methyl]phenolato)2(MeCOO)2(μ1,1-azide)2(MeOH)2 | 1096535-50-0

• 英文名称: [nickel(II)]3(2-[(2-isopropylaminoethylimino)methyl]phenolato)2(MeCOO)2(μ1,1-azide)2(MeOH)2
• CAS: 1096535-50-0
• 化学式: C₃₀H₄₈N₁₀Ni₃O₈
• 分子量: 852.843
• InChiKey: RBLNYAJLRRYXPY-SAGLSTHRSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 nickel(II) acetate tetrahydrate 、 2-[(((2-propylamino)ethyl)imino)methyl]phenol 、 sodium azide 以 甲醇 、 乙醇 为溶剂， 以68%的产率得到[nickel(II)]3(2-[(2-isopropylaminoethylimino)methyl]phenolato)2(MeCOO)2(μ1,1-azide)2(MeOH)2
  参考文献：
  名称：

  Synthesis, Characterization, and Crystal Structure of a Novel Trinuclear Schiff Base Nickel(II) Complex

  摘要：

  A novel azide and acetate bridged linear trinuclear Schiff base nickel(II) complex, [Ni{Ni(C12H17N2O)(MeCOO)(mu(1,1)-N-3)( MeOH)}(2)], has been synthesized and characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. There are 3 bridges across the Ni center dot center dot center dot Ni atom pairs, involving 1 phenolate oxygen atom of the Schiff base ligand 2-[(2-isopropylaminoethylimino)methyl] phenolate, 1 O-C-O bridge of the acetate group, and 1 mu(1,1) (end-on, EO) azide group. The central Ni atom is located on an inversion centre and has an octahedral coordination. The coordination around each terminal Ni atom is also octahedron. The Ni center dot center dot center dot Ni distance is 3.086(2) angstrom.

  DOI：

  10.1080/15533170701608924