[(Ph3PNC(C6H4)C(Ph)=N(4-MeC6H4)PdCl2] | 1160221-90-8

• 英文名称: [(Ph3PNC(C6H4)C(Ph)=N(4-MeC6H4)PdCl2]
• CAS: 1160221-90-8
• 化学式: C₃₈H₃₁Cl₂N₂PPd
• 分子量: 723.977
• InChiKey: BVFANTDMXALWSE-MDMSKSMXSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(Ph3PNC(C6H4)C(Ph)=N(4-MeC6H4)PdCl2] 以 二氯甲烷 、 氯苯 、 乙腈 为溶剂， 生成 [(C6H4P(Ph)2NC(C6H4)C(Ph)=N(4-MeC6H4))Pd(NCCH3)]BF4
  参考文献：
  名称：

  Reversible Orthopalladation of Phosphinimine−Imine Dichloropalladium(II) Complexes

  摘要：

  The synthesis and characterization of triphenylphosphinimine-arylimine bidentate ligands (aryl = 2,4,6-trimethylphenyl or 4-methylphenyl) along with their dichloropalladium(II) complexes are reported. These complexes form tridentate orthopalladated species upon heating in the presence or sodium acetate. The reverse reaction occurs upon addition of HCl center dot Et2O. The rate of orthopalladation and reprotonation is highly dependent on the steric bulk of the ligand. Related cationic species were also synthesized and characterized and found to be inert in the presence of 1-hexene and styrene.

  DOI：

  10.1021/om900194s
• 作为产物：
  描述：

  [(C6H4P(Ph)2NC(C6H4)C(Ph)=N(4-MeC6H4))PdCl]*CH2Cl2 、 hydrochloric acid diethyl ether 以 氯仿 为溶剂， 以85%的产率得到[(Ph3PNC(C6H4)C(Ph)=N(4-MeC6H4)PdCl2]
  参考文献：
  名称：

  Reversible Orthopalladation of Phosphinimine−Imine Dichloropalladium(II) Complexes

  摘要：

  The synthesis and characterization of triphenylphosphinimine-arylimine bidentate ligands (aryl = 2,4,6-trimethylphenyl or 4-methylphenyl) along with their dichloropalladium(II) complexes are reported. These complexes form tridentate orthopalladated species upon heating in the presence or sodium acetate. The reverse reaction occurs upon addition of HCl center dot Et2O. The rate of orthopalladation and reprotonation is highly dependent on the steric bulk of the ligand. Related cationic species were also synthesized and characterized and found to be inert in the presence of 1-hexene and styrene.

  DOI：

  10.1021/om900194s