1-ferrocenyl-2-isopropenyl-3,3-dimethylallylium tetrafluoroborate | 790677-15-5

• 英文名称: 1-ferrocenyl-2-isopropenyl-3,3-dimethylallylium tetrafluoroborate
• CAS: 790677-15-5
• 化学式: BF₄*C₁₈H₂₁Fe
• 分子量: 380.016
• InChiKey: KUIRNGJOBZLJRT-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  3-ferrocenylmethylidene-2,4-dimethylpenta-1,4-diene 、 1-ferrocenyl-2-isopropenyl-3,3-dimethylallylium tetrafluoroborate 在 N,N-dimethylaniline 作用下， 以 二氯甲烷 为溶剂， 以10%的产率得到7-ferrocenyl-4-ferrocenylmethylidene-8-isopropylidene-1,3,5-trimethyl-bicyclo[3.3.1]non-2-ene
  参考文献：
  名称：

  Cross-conjugated 3-ferrocenylmethylidene-2,4-dimethylpenta-1,4-diene in cationic cycloaddition and proton-catalyzed cyclodimerization reactions

  摘要：

  Cationic cycloaddition of cross-conjugated 3-ferrocenylmethylidene-2,4-dimethylpenta-1,4-diene to 1-ferrocenyl-2-isopropenyl-3,3-dimethylallylium tetrafluoroborate and its proton-catalyzed cyclodimerization result in diferrocenylbicyclo[3.3.1]nonene derivatives. The spatial structure of one of the reaction products, viz., ferroceno[4,5]-{9-ferrocenylmethylidene-1, 3,3,8, 10-pentamethyltricyclo[6.3. 1.0(2,6)]dodec-2(6)-ene), was established based on the data from X-ray diffraction analysis. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.07.031
• 作为产物：
  描述：

  四氟硼酸-二乙醚络合物 、 3-ferrocenylmethylidene-2,4-dimethylpenta-1,4-diene 以 乙醚 为溶剂， 以90%的产率得到1-ferrocenyl-2-isopropenyl-3,3-dimethylallylium tetrafluoroborate
  参考文献：
  名称：

  Cross-conjugated 3-ferrocenylmethylidene-2,4-dimethylpenta-1,4-diene in cationic cycloaddition and proton-catalyzed cyclodimerization reactions

  摘要：

  Cationic cycloaddition of cross-conjugated 3-ferrocenylmethylidene-2,4-dimethylpenta-1,4-diene to 1-ferrocenyl-2-isopropenyl-3,3-dimethylallylium tetrafluoroborate and its proton-catalyzed cyclodimerization result in diferrocenylbicyclo[3.3.1]nonene derivatives. The spatial structure of one of the reaction products, viz., ferroceno[4,5]-{9-ferrocenylmethylidene-1, 3,3,8, 10-pentamethyltricyclo[6.3. 1.0(2,6)]dodec-2(6)-ene), was established based on the data from X-ray diffraction analysis. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.07.031